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Naming Ionic Compounds with Multivalent Cations
 

How to Name Ionic Compounds with Multivalent Cations

Name the following multivallent ionic compound: Cu3PO3

Description of Action
Action
1. Name the cation. 1. copper
2. Check your periodic table to see if the element has more than one charge. If it does, write empty parenthesis after the cation’s name. 2. Yes its has charges of 1+ and 2+.
copper( )
3. Name the anion. At the bottom of the parenthesis, write the possible charges. Your Roman Numeral can only be one of these charges. 3. copper( 1,2 ) phosphite
4. Look at your formula. If they are not already written, put parenthesis around any polyatomic ions. 4. Cu3(PO3) Phosphite is polyatomic, so I put parenthesis around it. Copper is not polyatomic, so it does not need parenthesis.
5. Write the anion’s charge to the top right of its symbol, outside of the parenthesis. 5. Cu3(PO3)3-
6. Multiply the anion’s charge and the anion’s subscript. If the anion is polyatomic, use the subscript outside of the parenthesis. If there is no number written, we must assume it is one. 6. For this formula we would multiply 3- (charge) x 1 (subscript).
3 x 1 = 3
7. Divide the result by the subscript of the cation. Again, if there is no number written, assume the subscript is one. 7. Our result was (3) and the subscript of copper (the cation) is 3, so we would divide: 3 ÷ 3 = 1
8. Your new result is the Roman Numeral to put in parenthesis after the cation’s name. Be sure to check your periodic table to verify that the number you use is valid. 8. copper(I) phosphite
9. Since copper(I) is also known as cuprous, you can also write the common name. Either is acceptable. 9. cuprous phosphite

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